twitter

Friday, 13 May 2016

Dill and parsley seed extracts in scale up synthesis of aminopolyalkoxybenzenes – beneficial synthons for fused nitrogen polyalkoxyheterocycles

Volume 26, Issue 1, January–February 2016, Pages 66–68

Ecologically friendly transformation of readily accessible plant allylpolyalkoxybenzenes to hardly available aminotetraalkoxybenzenes has been developed. The efficacy of hydrogenation stage is substantially increased by the application of highly porous ceramic block Pd-catalysts featuring a large surface area, low hydraulic resistance, significant thermal and mechanical stabililty, multiple cycling and easy regeneration.

Graphical abstract


References

    • 8
    • A.T. Shulgin, A. Shulgin
    • Tinkal: The Continuation
    • Transform Press, Berkeley (1977), p. 646
    • 9
    • V.V. Semenov, V.A. Rusak, E.M. Chartov, M.I. Zaretskii, L.D. Konyushkin, S.I. Firgang, A.O. Chizhov, V.V. Elkin, N.N. Latin, V.M. Bonashek, O.N. Stas’eva
    • Russ. Chem. Bull., Int. Ed., 56 (2007), p. 2448 (Izv. Akad. Nauk, Ser. Khim., 2007, 2364)
    •  |   | 
    • 11
    • L.D. Konyushkin, T.I. Godovikova, S.K. Vorontsova, D.V. Tsyganov, I.B. Karmanova, M.M. Raihstat, S.I. Firgang, M.A. Pokrovskii, A.G. Pokrovskii, M.N. Semenova, V.V. Semenov
    • Russ. Chem. Bull., Int. Ed., 59 (2010), p. 2268 (Izv. Akad. Nauk, Ser. Khim., 2010, 2212)
    •  |   | 
    • 24
    • (a)A. I. Kozlov and E. S. Lukin, RF Patent 2233700, 2004.
    • 25
    • (a)N. I. Vavilov, V.L. Zbarsky, A.I. Kozlov, E.S. Lukin, E.N. Mizgunova, P.I. Fedotov and V. A. Chashtin, RF Patent 2164222, 2001.
    • (b)V. L. Zbarsky, N.V. Khodov, A.I. Kuimov and A. I. Kozlov, RF Patent 2333795, 2008.
    • (c) A.I. Kozlov, V.N. Grunskii, A.V. Bespalov, A.S. Novoselov, D.S. Grakova, A.A. Merkin, A.A. Komarov
    • Usp. Khim. Khim. Tekhnol., 22 (2) (2008), p. 49 (in Russian)
    •  | 

Supplementary data

Corresponding author. Fax: +7 499 135 5328.